It's crazy to think that it was almost 10 years ago that Brad Pitt and Angelina Jolie first laid eyes on one another on the set of their action film Mrs. and Mr. Smith. What could have been just another sexy action flick turned into one of the most buzzed about films — in part because we were viewing what was widely speculated to be the film where Pitt and Jolie first fell in love. We all know the controversy that surrounded the new Mr. and Mrs. Jolie-Pitt once upon a time, but they're hardly the first actor couple to find love at their place of work. Celebrities fall in love on set all the time — whether or not it works out after the movie or TV show wraps up is an entirely different story. Check out the 18 other celebrity couples who fell in love as the cameras rolled.
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